Fusing Dicarbollide Ions with N‐Heterocyclic Carbenes
نویسندگان
چکیده
منابع مشابه
Production of carbenium ions from carbenes by protonation
Diphenyl-, aryl-a-siloxyand %-furany1 carbenes can be protonated by even weak proton donors such as alcohols (by a bimolecular or by a pre-association mechanism involving more than one alcohol molecule) to yield the corresponding carbenium ions, whose spectra and electrophilic patterns of behavior are described. INTRODUCTION Proton transfer reactions to and from heteroatoms (= "normal" Bronsted...
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1,3-Disubstituted 2-azidoimidazolium salts (substituents = methyl, methoxy; anion = PF6) reacted with N-heterocyclic carbenes to yield yellow 2-(1-(azolinylidene)triazen-3-yl)-1,3-R2imidazolium salts (azole = 1,3-dimethylimidazole, 1,3-dimethoxyimidazole, 4-dimethylamino-1methyl-1,2,4-triazole; R = methyl, methoxy; anion = PF6). Crystal structures of three cationic triazenes were determined. Nu...
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[figure: see text] Benzocyclopropene and cyclopropa[b]naphthalene react with dichloro-bis(tricyclohexylphosphine)methylideneruthenium, incorporating the metallacarbene to form unstable 3-ruthenacyclopentenes, which decompose to give o-xylylenes that can be trapped as Diels-Alder adducts by dimethyl acetylenedicarboxylate. In contrast, bis(eta 5-cyclopentadienyl)methylidenetitanium forms moderat...
متن کاملN-Heterocyclic carbenes
The N-heterocyclic carbenes (NHC) now hold a preferredligand status in organic and organometallic chemistry. Their role in catalysis continues to grow. When the editorial staff at the Beilstein Journal of Organic Chemistry contacted me to act as a guest editor for the thematic series “N-Heterocyclic carbenes”, I was more than happy to accept what appeared to me to be a simple and exciting endea...
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In regard to the worldwide interest in synthesis and application of stable carbenes, DFT calculations (B3LYP/6-311++G**//B3LYP/6-31+G* levels) are employed to reach at a series of phenyl carbenes. The singlet-triplet energy separations (ΔES-T), HOMO–LUMO energy gaps (ΔEHOMO-LUMO), as well as philicity indices (N and ω) and basicity of these carbenes are compared and contrasted with the synthesi...
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ژورنال
عنوان ژورنال: Angewandte Chemie
سال: 2017
ISSN: 0044-8249,1521-3757
DOI: 10.1002/ange.201705857